Issue
Config Vars are limited to 64KB per application. The Platform will prevent you from attempting to store more than 64KB, but it can sometimes be helpful to know how much space is being used.
Resolution
You can calculate the size of your Config Vars via the CLI command:
$ heroku config --json -a APP_NAME | tr -d '[:space:]' | wc -c
13245
Here, the Config Vars are using ~13KB of space.